2-Amino-5-ethoxycarbonyl-4-methylthiazol-3-ium chloride monohydrate

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2-Amino-5-ethoxy­carbonyl-4-methyl­thia­zol-3-ium chloride monohydrate

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Crystal structure of 2-amino-5-methyl­sulfanyl-1,3,4-thia­diazol-3-ium chloride monohydrate

The title salt, C3H6N3S2 (+)·Cl(-)·H2O, crystallized with two organic cations, two chloride anions and two water mol-ecules in the asymmetric unit. The methyl C atoms deviate from their respective bound ring planes by 0.081 and 0.002 Å. In the crystal, the components are connected via N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds, forming sheets lying parallel to (100). The sheets are linked into bil...

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In the cation of the title salt, C(11)H(12)IN(4) (+)·Cl(-), the two aromatic rings are oriented to each other at 9.3 (2)°. In the crystal, the two independent Cl(-) anions lie on twofold rotation axes. N-H⋯Cl hydrogen bonds between the cations and anions generate a supra-molecular layer parallel to (010).

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809024532